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Can you mix baking soda and vinegar?

Baking soda and Vinegar
You can, but it achieves nothing
Safe, dramatic, and it leaves you with salt water.

What actually happens

Sodium bicarbonate is a base and vinegar is an acid, so they neutralise each other. The fizz is carbon dioxide escaping, and what remains in the bowl is a dilute solution of sodium acetate — salt water. Baking soda cleans because it is a mild abrasive and a base that cuts grease; vinegar cleans because it is an acid that dissolves limescale. Combining them destroys both properties and produces a cleaner weaker than either.

How people end up doing it

It is the single most shared cleaning tip on the internet, and the visual drama of the fizz is doing all the persuading.

What to do instead

Use them separately for what each is good at: bicarbonate as a gentle scouring paste, vinegar on limescale and glass. The one place the reaction is genuinely useful is mechanical — the gas can shift a light drain blockage by agitation, not by cleaning.

Cleaning products

Combination Verdict Why
Bleach and ammonia Toxic gas No. This is the classic household poisoning and it produces chloramine gas.
Bleach and vinegar Toxic gas No. Any acid plus bleach releases chlorine gas.
Bleach and toilet cleaner Toxic gas No. Most toilet cleaners are acidic, so this is the bleach-and-acid reaction.
Bleach and rubbing alcohol Toxic gas No. It produces chloroform and other chlorinated compounds.
Hydrogen peroxide and vinegar Do not No — mixed in a bottle it forms peracetic acid, which is corrosive.
One drain cleaner and a different drain cleaner Toxic gas No. Drain cleaners come in strongly acidic and strongly caustic types, and combining them is violent.
Bleach and hydrogen peroxide Do not No — it is exothermic and destroys both, and can spray hot liquid.
Vinegar and castile soap Pointless Safe, and it curdles into a white mess that is worse than either.
Vinegar and ammonia Pointless Not dangerous, and they cancel each other out.

Common questions

Can you mix baking soda and vinegar?
You can, but it achieves nothing. Safe, dramatic, and it leaves you with salt water.
What happens if you do?
Sodium bicarbonate is a base and vinegar is an acid, so they neutralise each other. The fizz is carbon dioxide escaping, and what remains in the bowl is a dilute solution of sodium acetate — salt water. Baking soda cleans because it is a mild abrasive and a base that cuts grease; vinegar cleans because it is an acid that dissolves limescale. Combining them destroys both properties and produces a cleaner weaker than either.
What should I do instead?
Use them separately for what each is good at: bicarbonate as a gentle scouring paste, vinegar on limescale and glass. The one place the reaction is genuinely useful is mechanical — the gas can shift a light drain blockage by agitation, not by cleaning.

Related pages

Sources

  1. US Environmental Protection Agency — EPA (Public domain (US Government))

How these figures are compiled and checked