At One Place

NFPA 704 fire diamond

NFPA 704 fire diamond
A US placard telling emergency responders how a stored chemical behaves in a fire.

What it looks like

A diamond of four smaller diamonds: blue on the left, red on top, yellow on the right, white at the bottom, each holding a number from 0 to 4 or a code.

What it means

Blue is health, red is flammability, yellow is instability or reactivity, and each runs 0 for no hazard to 4 for severe. The white square carries a special code: OX for an oxidiser, a W with a line through it for water-reactive, SA for simple asphyxiant. It is addressed to firefighters approaching a building, not to users of the product, so it describes a short intense exposure rather than the chronic hazards on a GHS label — which is why the two systems can rate the same substance differently and neither is wrong.

Defined by NFPA 704. Where a symbol differs between standards, the difference is described above rather than resolved — both versions are in circulation on real labels.

Other hazard warnings symbols

Symbol Means
Exploding bomb (GHS01) Explosive, self-reactive, or an organic peroxide that can explode.
Flame (GHS02) Flammable — or a substance that heats up, ignites in air, or gives off flammable gas when wet.
Flame over circle (GHS03) Oxidising — it will feed a fire, including one that has nothing else to burn with.
Gas cylinder (GHS04) Gas under pressure — compressed, liquefied, refrigerated or dissolved.
Corrosion (GHS05) Causes severe skin burns and eye damage, or corrodes metal.
Skull and crossbones (GHS06) Acute toxicity — fatal or toxic in small amounts by swallowing, skin contact or inhalation.
Exclamation mark (GHS07) Irritant, skin sensitiser, harmful if swallowed or inhaled, or may cause drowsiness — the lower-severity hazards.
Health hazard (GHS08) Serious long-term health effects — cancer, genetic damage, harm to fertility or the unborn child, organ damage, asthma from inhalation, or fatal if swallowed and it enters the airways.
Environment (GHS09) Hazardous to the aquatic environment — toxic to fish and other water life.
Orange explosive (E) Explosive, under the old European system.
Orange oxidising (O) Oxidising agent, under the old European system.
Orange flammable (F, F+) Highly flammable (F) or extremely flammable (F+), under the old European system.
Orange toxic (T, T+) Toxic (T) or very toxic (T+), under the old European system.
Orange harmful or irritant (Xn, Xi) Harmful (Xn) or irritant (Xi), under the old European system.
Orange corrosive (C) Corrosive, under the old European system.
Orange dangerous for the environment (N) Dangerous for the environment, under the old European system.
Biohazard Biological material that can cause disease — blood, cultures, clinical waste.
Radiation trefoil Ionising radiation — a radioactive source or a device producing radiation.
Laser radiation Laser radiation — do not look into the beam.

Common questions

What does the nfpa 704 fire diamond symbol mean?
A US placard telling emergency responders how a stored chemical behaves in a fire.
What does it look like?
A diamond of four smaller diamonds: blue on the left, red on top, yellow on the right, white at the bottom, each holding a number from 0 to 4 or a code.

Related pages

Sources

  1. Official vendor product documentation — At One Place

How these figures are compiled and checked