Which came first, Java or the World Wide Web?

the World Wide Web came first, by 6 years. Tim Berners-Lee wrote the proposal at CERN.

Side by side

Java

Java was announced in May 1995, having started in 1991 as a project called Oak aimed at interactive television — a market that did not exist yet. Its promise was "write once, run anywhere", achieved by compiling to bytecode for a virtual machine rather than to a specific processor. JavaScript arrived seven months later and was named after it purely as a marketing decision; the two languages are unrelated.

the World Wide Web

Berners-Lee circulated his proposal in March 1989, built the first browser and server by the end of 1990, and CERN put the software into the public domain in 1993. The Web is twenty years younger than the internet: the internet is the network, the Web is one service running on it, and email and file transfer both predate the Web by decades. The first website went live in December 1990 and is still online.