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Can you mix vinegar and ammonia?

Vinegar and Ammonia
You can, but it achieves nothing
Not dangerous, and they cancel each other out.

What actually happens

An acid and a base neutralise to produce ammonium acetate and water. It is not a hazardous reaction — this is the rare case where two cleaning products meet and nothing bad happens — but both are consumed and neither cleans afterwards. Ammonia is an excellent glass cleaner and vinegar an excellent descaler, and the mixture is neither.

What to do instead

One or the other, chosen for the job.

Cleaning products

Combination Verdict Why
Bleach and ammonia Toxic gas No. This is the classic household poisoning and it produces chloramine gas.
Bleach and vinegar Toxic gas No. Any acid plus bleach releases chlorine gas.
Baking soda and vinegar Pointless Safe, dramatic, and it leaves you with salt water.
Bleach and toilet cleaner Toxic gas No. Most toilet cleaners are acidic, so this is the bleach-and-acid reaction.
Bleach and rubbing alcohol Toxic gas No. It produces chloroform and other chlorinated compounds.
Hydrogen peroxide and vinegar Do not No — mixed in a bottle it forms peracetic acid, which is corrosive.
One drain cleaner and a different drain cleaner Toxic gas No. Drain cleaners come in strongly acidic and strongly caustic types, and combining them is violent.
Bleach and hydrogen peroxide Do not No — it is exothermic and destroys both, and can spray hot liquid.
Vinegar and castile soap Pointless Safe, and it curdles into a white mess that is worse than either.

Common questions

Can you mix vinegar and ammonia?
You can, but it achieves nothing. Not dangerous, and they cancel each other out.
What happens if you do?
An acid and a base neutralise to produce ammonium acetate and water. It is not a hazardous reaction — this is the rare case where two cleaning products meet and nothing bad happens — but both are consumed and neither cleans afterwards. Ammonia is an excellent glass cleaner and vinegar an excellent descaler, and the mixture is neither.
What should I do instead?
One or the other, chosen for the job.

Related pages

Sources

  1. US Environmental Protection Agency — EPA (Public domain (US Government))

How these figures are compiled and checked