At One Place

What is a Match made of?

What is a Match made of?
An oxidiser and a fuel in the head, with the phosphorus that starts it moved onto the striking strip.

The safety match works precisely because it is split in two: the phosphorus that provides the low ignition temperature lives on the box, not on the match, so a boxful cannot go up from friction in a pocket. That design, from Sweden in the 1840s and 1850s, replaced white phosphorus matches, whose vapour caused phossy jaw — necrosis of the jawbone — among matchmakers, a scandal that drove the 1888 London matchgirls' strike and an international ban under the Berne Convention of 1906. It is one of the clearest cases of a consumer product being redesigned around a workplace disease rather than a consumer risk.

Component by component

Every material is a choice, and the third column is the constraint that drove it.
Part Material Why that material
head potassium chlorate as oxidiser with sulfur or antimony trisulfide as fuel, in a glue binder The head carries its own oxygen supply, so once lit it burns regardless of how much air reaches it.
striking surface red phosphorus with powdered glass in a binder Friction converts a trace of red phosphorus to white phosphorus, which ignites in air at about 30 °C and sets the head off.
friction filler ground glass in both head and strip It concentrates the friction into hot points instead of letting the energy spread out as warmth.
stick aspen or poplar impregnated with ammonium phosphate, or waxed paperboard The impregnation stops the stick glowing on after the flame is out, which is what causes afterglow fires in a bin.
strike-anywhere heads phosphorus sesquisulfide in the tip It puts the ignition chemistry back in the head, so any rough surface works — and that is why they are restricted for transport.

Other around the house objects

Common questions

What is a Match made of?
An oxidiser and a fuel in the head, with the phosphorus that starts it moved onto the striking strip.
What is the head of a Match made of?
Potassium chlorate as oxidiser with sulfur or antimony trisulfide as fuel, in a glue binder. The head carries its own oxygen supply, so once lit it burns regardless of how much air reaches it.
What is the striking surface of a Match made of?
Red phosphorus with powdered glass in a binder. Friction converts a trace of red phosphorus to white phosphorus, which ignites in air at about 30 °C and sets the head off.

Related pages

Sources

  1. Typical range compiled from manufacturer specifications — At One Place

How these figures are compiled and checked